
Chain of Custody
Mass balance and book and claim models can help scale nascent clean technologies and drive industrial decarbonisation by diversifying suppliers of low-carbon products and offering greater flexibility to buyers.



How it works:
What are chain of custody models? Chain of custody refers to the custodial sequence of all organisations (supply chain) that take ownership or control of a product during production, processing, shipping and retail (physically and/or administratively). According to the International Organization for Standardization (ISO) definition in ISO 22095, chain of custody models create transparency in the value chain on ‘the origin of inputs material, product components, product outputs and the conditions under which they are produced.’iii Chain of custody models are used to link sustainability practices at a certain stage in the value chain with a claim at the end of the chain about a product, process, business or service.iv There are four notable chain of custody models that companies engage with: identity preservation, physical segregation, mass balance and book and claim. This toolkit focuses on mass balance and book and claim. These two models offer a flexibility that can support companies in facilitating green purchases and meaningfully investing in low-carbon products and decarbonisation solutions across the value chain. These approaches have typically arisen in cases where companies purchase products or commodities from common pools or distribution systems and where direct contracting with suppliers or traceability to individual points of origin is not feasible.
What are book and claim and mass balance models? A mass balance system matches input and output flows as they move through an interconnected system or supply chain over a specified timeframe.v It allows for the physical mixing of materials or products with a set of specified characteristics with materials or products without that set of characteristics. This is relevant for materials and fuels where physical segregation is too complex, administratively burdensome or not possible. For example, this approach allows for the co-feeding of bio-based, recycled and virgin feedstock into a network of chemical production plants over a specified timeframe. This is a cost-efficient solution that allows suppliers to scale the use of low-carbon feedstocks and leverage existing infrastructure, rather than setting up a segregated production system. Mass balance also incentivises investment from buyers, as they have greater confidence that the added value of these low-emissions chemical products will be recognised.
Under a book and claim chain of custody system, physical mixing of materials or products with a set of specified characteristics with materials or products without that set of characteristics is also allowed. Unlike in a mass balance system, in a book and claim system, the amount of materials or products with different characteristics do not need to be tracked and documented at each point in a distribution network. Instead, a book-and-claim system decouples environmental attributes from the physical product and converts them into tradable certificates or ‘book-and-claim units’, managed and transferred through a central registry to ensure integrity. This allows producers of low-carbon products to ‘book’ the carbon emissions reduction of a good manufactured in one place and corporate buyers to ‘claim’ the reductions for climate disclosures in a different place.vi For example, buyers can purchase the environmental attributes of SAF without physically tracing the product through their operations. This creates a market for SAF that is better placed to absorb the cost premium, while unlocking demand in geographies with limited production.
These models can enable investment in lower carbon inputs, particularly in the early stages of new commodities coming to market when investment hurdles are high and distribution systems are low.
What sectors can leverage this mechanism?

Mass Balance: GMA Chemicals will build market-based tools to remove financial and structural barriers to decarbonisation. Further research examines chain of custody models for chemicals, such as Enabling a Circular Economy for Chemicals with the Mass Balance Approach.

Book and Claim: Sustainable Aviation Buyers Alliance (SABA) continues to drive investment into high quality SAF. For more information, visit Sustainable Aviation Buyers Alliance (SABA) (flysaba.org).


Book and Claim: RMI explores the applicability of book and claim for steel at Structuring Demand for Low-Carbon Materials. The Sustainable Steel Buyers Platform is gathering insights into key market challenges to support the development of book and claims rules.

Mass Balance: Aluminium Stewardship Initiative (ASI) is a multi-stakeholder organisation that uses a mass balance to collaboratively foster responsible production and purchase across the aluminium value chain. For more information, visit ASI: mass balance.

Book and Claim: GMA is helping establish a working group of companies to design a book-and-claim framework for concrete. For more information, visit Cement & Concrete – Center for Green Market Activation (gmacenter.org).
What challenges does it solve?
Duration
The terms of the offtake agreement can be less rigid than a contract tied to a physical product with delivery schedules and firm ‘take or pay’ clauses. Purchasing through these chain of custody models does not require a long-term purchasing commitment.
Volume
These mechanisms offer higher flexibility on terms of offtake, including lower volume commitment for buyers.
Price
Leveraging a mass balance or book-and-claim chain of custody, rather than setting up a segregated supply chain, can be more affordable for buyers. This is especially true for complex value chains where the physical segregation of recycled content is practically and/or economically unfeasible.
Delivery terms
Chain of custody models rely on a consistent definition, often set by a certification scheme.
Technical definition
These chain of custody models can provide a lower delivery risk due to the diversification of suppliers compared to direct contract with a single party.
Enabling infrastructure
These mechanisms can provide a signal of market activity in a sector or geography that would spur investment in the development of enabling infrastructure. Additionally, the ability of businesses to offtake environmental attributes directly, regardless of the origin, can remove the logistical barriers associated with distribution and renewable energy infrastructure.
Regulatory uncertainty
Given the differing regulatory guidelines and incentive schemes across regions, these mechanisms help aggregate supply and demand through a global system. This solves potential shortages at the regional level due to local regulations and policies, thereby unlocking corporate demand in regions where production is currently limited.
Trust
Mass balance and book and claim, if well standardised, can create trust within the value chain through a consistent approach. Many schemes include certification, which further builds trust. Public blockchain networks can be used as a digital registry for the environmental attributes, offering advantages such as improved transparency, the avoidance of double counting and non-repudiation between counterparties and third-party verifiers on the registry.
C-Suite and board buy-in
The use of well-established chain of custody models such as mass balance and book and claim can derisk the investment decision for those in the C-suite by providing an industry-aligned approach.
Procurement capability
Purchasing through chain of custody models, including mass balance and book and claim, often aligns well with existing procurement processes. Decoupling the green product from the environmental attribute reduces the green premium of the product and makes it a more credible procurement option than in the absence of the chain of custody model.
Mechanism challenges
The clear and consistent communication of both mechanisms is critical to avoiding misrepresented claims with stakeholders, especially customers, consumers and regulators. Companies often view these models as interim solutions, while the ultimate goal remains fully traceable, segregated sustainable supply chains. Some have criticised these mechanisms as likely only supporting incremental emissions reductions, and therefore delaying the adoption of more stringent fully segregated supply chains with deeper decarbonisation.
Book-and-claim:
Standardisation and certification: It is critical that book-and-claim systems be centralised and standardised by sector, with clear criteria and safeguards and/or certified by a third party. Accurate accounting improves the integrity of the mechanism to ensure companies have the incentive to invest in supply chain decarbonisation. This entails clearly defining the system boundaries, including the participants allowed to trade and the units that relate to voluntary emissions reductions.
Consumer trust: Some stakeholders have concerns that the use of a book-and-claim approach by companies could decrease rather than increase decarbonisation by obscuring emissions, making it more difficult to identify mitigation opportunities, or by decreasing ambition for decarbonisation without a corresponding decrease in emissions. The development of the scheme must aim to mitigate double counting risks to ensure that emissions reductions claimed by a company correspond to a reduction in emissions to the atmosphere.
Market dependence: A fracturing of different programmes with varying objectives may also threaten the effectiveness of book-and-claim schemes.vii
Mass balance:
Standardisation and certification: Accurate accounting and reporting is fundamental to the integrity of mass balance market mechanisms. Volumes are tracked through the supply chain to ensure that quantities of materials or products purchased (that have a set of specified characteristics) match the quantities produced. This requires a robust, transparent and standardised system of certification and auditing, especially across international borders.
Consumer trust: Mass balance is subject to debate due to its complex nature, which makes it difficult to socialise. Value chains still require further alignment on allocation rules to ensure they address all actors’ needs to ensure transparency and a common understanding of the subsequent claims made through mass balance accounting.
Market dependence: A mass balance system provides economic efficiency advantages. There is a need for alignment in how both book-and-claim and mass-balance mechanisms can be leveraged for corporate accounting and target-setting. Work is currently underway by the Greenhouse Gas Protocol to provide new guidance on accounting and reporting for the impact of corporate actions and market instruments.

Case Studies: Aluminium Stewardship Initiative (ASI)

The Aluminium Stewardship Initiative (ASI) is a global non-profit standard-setting and certification organisation. ASI brings together producers, users and stakeholders in the aluminium value chain to collaboratively foster responsible aluminium production, sourcing and stewardship.
ASI defines standards for the responsible production and sourcing of aluminium from its mined or recycled source and through each step in the value chain to final products. The principles address key environmental, social and governance principles.
The ASI Chain of Custody Certificationviii uses a mass balance approach to link a company’s sustainability performance with its material outputs. The requirements can be independently audited to be certified. Under a mass balance approach, certified and non-certified material can be mixed, with the output then managed and allocated based on the percentage of input. In this way, the focus is on connecting the supply chain practices of the entities in the chain, not on atoms in the material. The system allows for the quality of material (ASI Bauxite, ASI Alumina and ASI Aluminium) to accompany shipments along the supply chain.
To meet the changing market needs, ASI’s chain of custody approach is evolving for the next revision of standards in 2027.
